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1. Identificação
Tipo de ReferênciaArtigo em Revista Científica (Journal Article)
Siteplutao.sid.inpe.br
Código do Detentorisadg {BR SPINPE} ibi 8JMKD3MGPCW/3DT298S
Identificador8JMKD3MGP3W/3SCS2DS
Repositóriosid.inpe.br/plutao/2018/12.14.19.43   (acesso restrito)
Última Atualização2018:12.18.15.26.33 (UTC) lattes
Repositório de Metadadossid.inpe.br/plutao/2018/12.14.19.43.22
Última Atualização dos Metadados2019:01.14.17.09.18 (UTC) administrator
DOI10.9734/JMSRR/2018/43664
ISSN2321-6212
Rótulolattes: 3273084621532688 3 CoutoPereFerr:2018:DoDiEl
Chave de CitaçãoCoutoPereFerr:2018:NiElRe
TítuloNitrate electrochemical reduction using modified boron-doped diamond electrode from Copper electroless
Ano2018
Data de Acesso03 maio 2024
Tipo de Trabalhojournal article
Tipo SecundárioPRE PI
Número de Arquivos1
Tamanho304 KiB
2. Contextualização
Autor1 Couto, Andréa Boldarini
2 Pereira, Carlos Felipe
3 Ferreira, Neidenêi Gomes
Identificador de Curriculo1
2
3 8JMKD3MGP5W/3C9JHU3
Grupo1 CMS-ETES-SESPG-INPE-MCTIC-GOV-BR
2
3 LABAS-COCTE-INPE-MCTIC-GOV-BR
Afiliação1 Instituto Nacional de Pesquisas Espaciais (INPE)
2
3 Instituto Nacional de Pesquisas Espaciais (INPE)
Endereço de e-Mail do Autor1
2
3 neidenei.ferreira@inpe.br
RevistaJournal of Materials Science Research and Reviews
Volume1
Número4
Páginas1-14
Histórico (UTC)2018-12-18 15:26:35 :: lattes -> administrator :: 2018
2019-01-14 17:09:18 :: administrator -> simone :: 2018
3. Conteúdo e estrutura
É a matriz ou uma cópia?é a matriz
Estágio do Conteúdoconcluido
Transferível1
Tipo do ConteúdoExternal Contribution
Tipo de Versãopublisher
Palavras-Chavediamante dopado
electroless
redução de nitrato
ResumoModified boron- doped diamond (BDD) electrodes from copper (Cu) electroless process were produced and characterised aiming their application at nitrate electrochemical removal. Cu deposits on BDD surface may promote its conductivity and selectivity increase mainly for nitrate ions reduction using the flow electrochemical reactor. Cu/BDD composites were obtained with optimised parameters to produce high- quality electrodes in suitable doping level associated with Cu particle deposits. BDD films were grown on titanium (Ti) substrates from hot filament chemical vapour deposition reactor. Higher deposit density as well as better Cu particles uniformity was observed for the highest doped BDD electrodes. Considering the nitrate reduction, four cathode and four anode electrodes with 2.5 × 2.5 cm2 were necessary for each electrolysis. The experiments were carried out by varying current density, reactor flow rate, and supporting electrolyte. The process effectiveness was analysed as a function of BDD/Ti and/or Cu/BDD/Ti electrodes as cathode where the results were monitored by Ion Chromatography. This analyses showed the highest electrolysis efficiency for 300 L h-1 flow rates, when BDD/Ti electrodes were used both as an anode and as cathode simultaneously. These results were corroborated by X-ray photoelectron spectroscopy (XPS) measurements for electrode surfaces before and after the electrolysis. This behaviour may be associated with the lower impurity adsorption on the film surface due to the turbulent regime used in the flow reactor. On the other hand, when Cu/BDD/Ti was used as a cathode, the best efficiency was obtained for the flow rate of 50 L h-1 , which may be associated to the low hydrogen adsorption on the electrode surface due to the Cu presence.
ÁreaFISMAT
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Conteúdo da Pasta docacessar
Conteúdo da Pasta sourcenão têm arquivos
Conteúdo da Pasta agreementnão têm arquivos
4. Condições de acesso e uso
Idiomaen
Arquivo Alvocouto_nitrate.pdf
Grupo de Usuárioslattes
Grupo de Leitoresadministrator
lattes
Visibilidadeshown
Permissão de Leituradeny from all and allow from 150.163
Permissão de Atualizaçãonão transferida
5. Fontes relacionadas
Unidades Imediatamente Superiores8JMKD3MGPCW/3ESR3H2
8JMKD3MGPCW/3F358GL
Lista de Itens Citandosid.inpe.br/bibdigital/2013/09.24.19.30 2
sid.inpe.br/mtc-m21/2012/07.13.14.56.52 1
sid.inpe.br/bibdigital/2013/10.14.21.39 1
Acervo Hospedeirodpi.inpe.br/plutao@80/2008/08.19.15.01
6. Notas
Campos Vaziosalternatejournal archivingpolicy archivist callnumber copyholder copyright creatorhistory descriptionlevel dissemination e-mailaddress format isbn lineage mark mirrorrepository month nextedition notes orcid parameterlist parentrepositories previousedition previouslowerunit progress project rightsholder schedulinginformation secondarydate secondarykey secondarymark session shorttitle sponsor subject tertiarymark tertiarytype url
7. Controle da descrição
e-Mail (login)simone
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